Blind Unmixing of Linear Mixtures using a Hierarchical Bayesian Model. Application to Spectroscopic Signal Analysis

  • Authors:
  • Nicolas Dobigeon;Jean-Yves Tourneret;Said Moussaoui

  • Affiliations:
  • IRIT/ENSEEIHT/TéSA, 2 rue Charles Camichel, BP 7122, 31071 Toulouse cedex 7, France. dobigeon@enseeiht.fr;IRIT/ENSEEIHT/TéSA, 2 rue Charles Camichel, BP 7122, 31071 Toulouse cedex 7, France. tourneret@enseeiht.fr;IRCCyN - CNRS UMR 6597, ECN, 1 rue de la Noë, BP 92101, 44321 Nantes cedex 3, France. said.moussaoui@irccyn.ec-nantes.fr

  • Venue:
  • SSP '07 Proceedings of the 2007 IEEE/SP 14th Workshop on Statistical Signal Processing
  • Year:
  • 2007

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Abstract

This paper addresses the problem of spectral unmixing when positivity and additivity constraints are imposed on the mixing coefficients. A hierarchical Bayesian model is introduced to satisfy these two constraints. A Gibbs sampler is then proposed to generate samples distributed according to the posterior distribution of the unknown parameters associated to this Bayesian model. Simulation results conducted with synthetic data illustrate the performance of the proposed algorithm. The accuracy of this approach is also illustrated by unmixing spectra resulting from a multicomponent chemical mixture analysis by infrared spectroscopy.