Identification of parameters in polymer crystallization

  • Authors:
  • Daniele Andreucci;Monica Bianchini;Aldo Pasquali

  • Affiliations:
  • Dipartimento di Metodi e Modelli Matematici per le Scienze Applicate, Università di Roma La Sapienza, Via A. Scarpa 10, 00161 Roma, Italy;Dipartimento di Sistemi e Informatica, Università di Firenze, Via di Santa Maria 3, 50139 Firenze, Italy;Dipartimento di Energetica, Università di Firenze Via C. Lombroso 6/17, 50134 Firenze, Italy

  • Venue:
  • Applied Numerical Mathematics
  • Year:
  • 1995

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Abstract

The complex phenomenon of partial crystallization of polymers is examined. A mathematical model is exploited for the isothermal crystallization process in which the nucleation rate and the growth of the spherulites are constant. This model consists of an integro-differential equation, depending on some key parameters, whose identification is crucial for a correct description of the phenomenon. The main purpose of this work is to solve this problem numerically, using the experimental data provided by the HIMONT-ITALIA Laboratories. An error analysis of the adopted numerical method is carried out, and some numerical results are given, to show the validity and flexibility of the technique.