Optimization of activity coefficient models to describe vapor-liquid equilibrium of (alcohol + water) mixtures using a particle swarm algorithm

  • Authors:
  • Juan A. Lazzús

  • Affiliations:
  • -

  • Venue:
  • Computers & Mathematics with Applications
  • Year:
  • 2010

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Abstract

A method to model the vapor-liquid phase based on a particle swarm algorithm is developed in this study. Two activity coefficient models (UNIQUAC and NRTL) were optimized with particle swarm optimization (PSO), and used to describe the isobaric vapor-liquid equilibrium of fifteen binary mixtures containing alcohol + water. The results were compared with the Levenberg-Marquardt algorithm, and show that the PSO algorithm is a good method to correlate and predict the vapor-liquid equilibrium of this type of system.